Mast
Understanding filtration: Cartridges

Part 1
he various types of filtration systems used in our industry have “come and gone” several times over the past 70 years. From the heavy canvas covered screens, to the fine mesh stainless steel, or monel,
screens, to the rigid tubes, to the regenerative tubes, to the perpendicular stainless discs, to the cartridges, to the centrifugal discs with filter powder, to the powderless centrifugal disc and to the final combination of powderless centrifugal disc with cartridges as carbon towers.
Carbon also has changed its form over the years from finely-ground activated powder to granules of activated chips. Although, some of the users of diatomaceous earth (filter powder) are using the carbon powdazer as part of the pre-coating process. A comprehensive discussion of activated carbon will be made later in this series.
During the 1960s and early 1970s the regenerative powder filter gave way to the much more convenient cartridge filter. Although the filter powder and activated carbon powder pre-coat gave excellent results, there were problems with the pre-coat breaking up to damage the load together with the sloppy procedure in handling the spent powder residue from the muck cooker.
This was the result of not “cooking” the spent powder and carbon, with its non-volatile residue, completely to include the steam, or air, sweep to attain a bone dry residue. Also, the filter powder added more disposable waste which later became a legal issue as well as being costly to haul away.
The cartridge filter has many advantages over the older methods of filtration:
1. Convenience and simplicity.
2. No damage to garments when expended or under reduced solvent flow.
3. Easy to store.
4. Can be used the next day without any procedures.
5. Can be checked for performance easily by observing gauge or flow meter.
6. Lower cost than filter powder.
7. Long life through use of high performance pump and pre-lint or disc filter.
8. No purchase of extra cartridges need be made until the presently used ones are almost ready to be replaced.
9. After the activated carbon and carbon/clay combination cartridges are spent, most of their solvent content can be azeotroped and “cooked out.”
There are several types of cartridges in use today with various adsorption materials and also without adsorption materials (all paper). Cartridges come in three basic sizes: standard (7" diameter, 14" high), full size jumbo (13" diameter, 18" high) and jumbo “split” (13" diameter, 9" high).
All three come with pleated paper only, and the jumbo cartridges also come with activated carbon granules in the center or with a combination of activated carbon granules and heat-treated attapulgite clay.
This last type of cartridge adsorbs the following in consecutive order (the first being the greatest adsorbed):
Water
Alcohols
Acids
Aldehydes
Ketones
Olefins
Natural esters
Aromatics
Cyclo-paraffins
Paraffins.
The activated carbon chips adsorb dyes primarily.
The amount of carbon contained in the standard size cartridge is 2 pounds, and the total square feet of filter surface area is 38.6.
The amount of carbon contained in the all-carbon standard size cartridge is 8 pounds, and this cartridge is never used for filtering insoluble soil since its only function is conditioning of the solvent to remove dyes, essentially, with some other soluble soil also removed.
The amount of carbon contained in the jumbo full-size cartridge is 16.5 pounds, and the total square feet of filter surface area is 69.3. The amount of carbon contained in the jumbo split size cartridge is 8 pounds, and the total square feet of filter surface area is 34.2.
The jumbo full size, or split size, cartridge with activated carbon and pleated paper only can serve as an excellent carbon tower for primary filters of all paper cartridges or spin disc filters.
Some manufacturers of cleaning machines offer a special size canister which holds one or two knit bags of activated carbon granules as a carbon tower for solvent conditioning only.
The main disadvantage of this knit bag of carbon is the messy handling of the carbon bag after it has been spent since it is almost impossible to azeotrope the solvent out within the still without bursting the bag.
The jumbo full-size adsorption cartridge contains 8 pounds of activated carbon and 14 pounds of the extruded and heat-treated attapulgite clay. The jumbo split size adsorption cartridge contains 4 pounds of activated carbon and 7 pounds of the extruded and heat-treated attapulgite clay.
Some filter cartridge manufacturers market these filters as substitutes for distillation, especially for petroleum solvent users with older transfer units or dry-to-dry units without a still. However, this author strongly adheres to distillation to condition solvent in addition to any form of cartridge filtration.
Composition of a cartridge filter
1. Outer shell (not used by all manufacturers)
As the solvent flows into the filter housing, or canister, it strikes the metal perforated outer shell which protects the pleated paper and also traps large portions of lint. The number of perforations and their size must total not less than the aggregate size of the holes in the paper in order to maintain the proper flow rate of
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solvent.
The flow rates for perchloroethylene are: 3 gallons per minute (gpm) for a standard size cartridge, 2.7 gpm for a jumbo split size cartridge and 5.4 gpm for jumbo full size cartridge. The flow rates for hydrocarbon/petroleum solvent are approximately one gpm more than those for perchloroethylene due to the lighter weight of the hydrocarbon/petroleum solvent.
The outer shell also gives more overall strength to the cartridge in addition to keeping excessive amounts of lint off the paper. The installation of a pre-lint filter, or centrifugal disc filter, will add much more filtering life to the paper.
The jumbo full size filter cartridge does not contain a perforated outer shell. To use this cartridge as an adsorptive device with activated clay and carbon, the manufacturers prefer the flow rate of solvent to be somewhat restricted in order to have the solvent “channel” over the adsorptive bed.
This permits the soluble soils and non-volatile residue (NVR) to adhere to the pores of the adsorptive material.
2. Pleated paper element
The solvent flows next through the pleated paper element. Each standard size cartridge contains about 5,770 square inches (40 square feet) of pleated paper. The paper is made by the wet-formation paper-making process, and it is treated with a phenolic-formaldehyde resin which is applied to the paper in its uncured form.
Next, the pleating takes place, and, finally, the resin is cured on the paper in an oven at a high temperature. The cured resin gives the paper wet strength, stiffness and rigidity.
The purpose of the pleated paper is to remove the insoluble soil from the solvent by entrapping these particles in the small pores of the pleated paper. These pores are from 30 to 40 microns in diameter. A micron = 39/1,000,000 of an inch.
The insoluble soil particles, which are suspended in the solvent, are removed by either of the following three methods:
Mode A: The pores in the pleated paper gradually become clogged if the particles are larger than the pores.
Mode B: The particles are smaller than the pores through which they are passing, and they are being trapped on the edges.
These insoluble particles are being held by an electrostatic, or physical, attraction known as “Vander Waals Forces.”
Vander Waals was a Dutch physicist who discovered the process of adsorption (by attraction to certain elements and minerals) which is similar to metal shavings being attracted to a magnet and filtration by congregation of materials.
Mode C: One layer of particles is deposited on the pleated paper, and this layer is followed by subsequent layers that build up a thickness (as a cake). The layers serve as a filter within the filter of small pores with the microscopic openings between the particles and layers allowing the solvent to pass through.
In the early stages of a new set of cartridges, a flow rate of one gallon of solvent per pound of garments per minute, which is ideal for complete removal of insoluble soil from the garments and from the drum in an expeditious manner, will prevent the insoluble particles from quickly congregating on the pleated paper (as in Mode C).
To alleviate this condition, and to cause the particles to congregate and encounter Vander Waals forces, it is best to slow down the flow rate of solvent by partially closing a solvent flow control valve (located at the downstream side of the filter pump or just before the filter housing or canisters). This valve should be a good quality gate valve, and it should be regulated to reduce the flow rate by about 15 percent.
Also, if you have a pre-lint filter installed before the primary filter, the bag should be removed from the canister for the first few hundred pounds of cleaning.
When about one pound of inlet pressure has been created on the filters, the bag can be inserted into the canister of the pre-lint filter and the solvent flow control valve can be readjusted for a one gallon of solvent per pound of garments per minute flow rate.
Initially, the very small (1-10 microns) insoluble particles not only pass through the pores of the pleated paper, they congregate, partially, in the very tiny spaces between the carbon chips of a carbon core, or all carbon, cartridge. These tiny spaces between the carbon chips are called "interstices.”
Since the insoluble particles and the carbon chips are not porous, the blockage of the interstices will greatly restrict the solvent flow rate. This condition, therefore, is alleviated by restricting the solvent flow rate during the first few hundred pounds of cleaning as described in the previous paragraph. If all paper (carbonless) cartridges are used, some insoluble particles can redeposit on the garments being cleaned. Using a high performance curve pump, capable of pumping up to 60 psi pressure, will greatly extend the filtration life of the pleated paper after its pores have been clogged with insoluble soil particles (with the solvent flow control valve wide open).
3. Inner shell
This shell has openings that are considerably smaller than those in the outer shell. It prevents the pleated paper from collapsing under the pressure of the solvent flowing through the continually decreasing diameter of the pores.
The perforated inner shell also retains the carbon/clay chips that are stored in that center chamber, and it provides some support to the carcass of the cartridge.
4. Inner chamber
This chamber contains the carbon, or carbon/clay, through which the solvent flows. These materials are not porous, and the solvent has to channel through the small interstices between the chips.
5. Center tube (outlet)
The filtered and purged solvent finally exits through the center tube. This tube can be made from a resin-treated laminated paper or perforated metal, and it is wrapped with either nylon or polypropylene to prevent any fine insoluble particles, or dust, from being carried out of the cartridge and into the cleaning machine’s drum to damage the load with loose carbon and soil particles.
Additional protection against this cartridge leakage of fine insoluble particles is with the use of felt washers, or pads, placed between each cartridge and on the ends of the first and last cartridge in the filter housing.  The felt pads will adsorb the insoluble particles as the solvent passes through them. They also serve as an adsorbent seal between the metal top and bottom cartridge covers of each cartridge and the end plates of the housing.
Factors on the construction of cartridge filters
1. The carton, filter shell and handles must be rugged enough to withstand shipment, handling and installation without damage.
2. A solid mechanical seal between the center tube and the shell, which does not fail and permit leakage when the cartridge is tightened down under the felt gasket.
3. Solid spacers to prevent the folds of the filter paper from collapsing on each other in handling or use.
4. Heavy weight, resin-impregnated filter paper properly crimped and cured must be used.
Next month I will discuss activated carbon and activated clay together with practical applications and uses of cartridge filtration.


Note: My spotting video, “The Caplan Method of Stain Removal,” which includes my comprehensive text and the handy spotting board reference, is available in English, Korean (video only) and Spanish (video only) from the Golomb Group, c/o Dennis McCrory, 7664 Plaza Court, Willowbrook, IL 60521, phone (800) 679-5856. A lecture and demonstration are presented similar to my classes over the years at IFI and SDA. This video and text are ideal for training inexperienced spotters as well as a good review for experienced spotters.
Also available from the Golomb Group, in English and Spanish, is my video on step-by-step shirt finishing which includes my comprehensive text in loose-leaf form (English only) outlining each procedure for a single-operator and two-operator cabinet shirt unit using a cabinet sleever. Proper forming of the collar using heated collar formers is demonstrated. Each lay is demonstrated for top quality with very little effort by the operators. Attractive detailing and packaging of the hangered shirt, padding, steam pressures and timing are all discussed. A unique wash formula to give whiter whites, brighter colors and total removal of grease and body oils is included in the loose-leaf note book.

Stan Caplan has over 35 years experience in his own high volume dry-cleaning, laundry and tailoring plant and two package plants with adjoining coin-operated laundry and drycleaning. Stan is the former chief instructor at the International Fabricare Institute, the Southwest Drycleaners Association and various other trade association-sponsored schools throughout the US and courses in Canada, Mexico, South Africa, Singapore and Hong Kong. Stan offers consulting, training and engineering services in all areas from customer service area to the boiler room since 1981. His complete system withtotal quality management will produce maximum efficiency, economy and product excellent quality. Stan can be reached at 7341 Amberly Lane, Suite 310, Delray Beach, FL 33446, phone/fax (561) 496-2548. His e-mail address is stancap100@aol.com.


Stan Caplan
OnDrycleaning
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A cross-section view of a typical cartridge filter. 1) Perforat
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