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Techniques for removing ink stains
nk stains are classified as dryside or wetside depending on the solvent or substance on which the pigment (dye) is dissolved or disbursed.
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Dryside inks are pigments disbursed in an oil, wax or grease base. Sometimes a binder is added for permanence.
Examples of dryside inks are marking ink, printing ink, ball point ink, India ink, carbon paper, stamp padding and some inks used in felt tip magic marker pens.
Wetside inks are dyes dissolved in water to which is added a setting agent such as gallic acid. Examples of wetside inks are some felt tip and magic marker pens.
The ingredients of both dryside and wetside inks which have been described are not complete since there are many variations.
Inks are formulated for their permanence in use so even stains from so called washable inks are difficult to remove.
Success in stain removal depends upon how long the ink stains have been in the fabric, the fastness of fabric color and the tenacity of the staining pigment or dye to the fabric.
Ink stain procedure
Dryside stain removal is the best procedure to use when attempting ink stain removal. It is the safest method to use and makes the wetside method easier.
The dryside method requires using oil-type paint remover, amyl acetate, mechanical action and then drycleaning.
The wetside stain removal process requires that you use the proper lubrication, which is using a non-ionic wetside detergent. These detergents provide the best lubrication for wetside ink stain removal eliminating the need for a neutral lubricant.
I would still use glycerin as a lubricant only for its safety on wools, silks and delicate colors.
An example of non-ionic detergents are those found in Laundry Targo by Wilson, Laundry Wetspo by Laidlaw and similar products used by other manufacturers.

Wetside method, except red:
1. Flush-Use water gun to avoid setting and spreading the stain.
2.  Non-ionic detergent.
3. Mechanical action.
4. Flush.
5. Non-ionic detergent plus acetic acid.
6. Mechanical action.
7. Flush.
8. Oxalic acid — Test.
9. Heat.
10. Flush.
11. General formula — Test.
12. Mechanical action.
13. Flush.
14. Rust remover — Test.
15. Heat.
16. Flush

Wetside inks (red)
The process for red inks is similar to the ink stain procedure outlined above. The only difference is that we use an additional step of ammonia and non-ionic detergent with the necessary mechanical action. This step would be used before using acetic acid and non-ionic detergent.
We would use this additional step because alkali such as ammonia bleed red inks and dyes more readily than acids. In cases of delicate colors, however, this step would be eliminated.
Advanced bleaching for last traces of ink stains
Hydrogen peroxide, 6% 20 volume
Procedure:
Wet area.
Apply lubricant.
Peroxide and ammonia.
Heat.
Flush.
Acetic Acid.
Heat.
Flush

Sodium perborate and sodium percarbonate
These bleaches are both obtained in powder form and they are alkaline in nature. They come in many products including all color safety bleaches for home use.
For proper spot bleaching order the pure product from your jobber. Use this bleach the same way that you would use hydrogen peroxide as previously outlined.
Sodium hydrochlorite or chlorine bleach
Dilute 5.25% chlorine with 50% water.
Procedure:
Wet area.
Apply lubricant.
Apply bleach.
Heat.
Flush.
Acetic acid.
Flush.
Please note that this bleach can not be used on wool or silk.
Pottasium permanganate.
A strong oxidizing bleach that comes in purple crystals. Wilson Chemical sells a liquid permanganate for ink removal that is very effective.
Procedure:
Wet area.
Apply lubricant.
Apply permanganate.
Heat.
Flush.
A brown discoloration is reduced by using either peroxide plus acetic or oxalic acid.
Flush
Sodium bisulphite (reducing bleach).
This is the safest reducing bleach that can be used for ink stains.
Procedure:
Wet area.
Apply lubricant.
Apply bisulphate.
Heat.
Apply acetic acid.
Flush.
Sodium hydosulphite.
A strong reducing bleach that comes in powder form.
Procedure:
Wet area.
Apply lubricant.
Apply hydrosulphite.
Heat.
Apply acetic acid.
Heat.
Flush.
Titanium sulphate.
Reducing bleach that comes in a black liquid.
Procedure:
Place towel under fabric.
Wet area.
Apply stripper with q-tip.
Heat.
Apply rust remover.
Heat.
Flush.
Protein formula or alkali to neutralize effects of rust remover.
Flush.
Important: All bleaches must be tested for safety to color and fabric before using.


Dan Eisen recently retired as chief garment analyst for the Neighborhood Cleaners Association after 33 years with that organization. He is available for seminars, consultations and independent garment analysis. He also has published a book, “The Art of Spotting,” which is an indexed compilation of articles he wrote for National Clothesline and NCA over the past three decades. He can be reached at (772) 340-0909. His address is 274 NW Toscane Trail, Port St. Lucie, FL 34986. His e-mail address is cleandan@adelphia.net.